Search results for "Poly n-butyl methacrylate"

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Solidification behavior of the theta system 2-propanol/poly(n-butyl methacrylate) I. Influences of thermoreversible gelation on stationary flow

1994

Zero shear viscosities, η0, were determined by means of a magnetoviscometer for melts of poly(n-butyl methacrylate) (M = 8.7 to 450 kg/mol, T =53.5 to 200°C) and for concentrated solutions of the highest molecular weight sample in isopropanol (T = 34.8 to 131.5 °C). Master curves can be constructed in both cases if the reference temperature is set proportional to the gelation temperature of the particular fluid. Special intersegmental interactions (eventually leading to thermoreversible gelation) can above all be felt in η0 (T) and in M c , the critical molecular weight determined in plots of log η0 vs. log M. As the temperature is lowered, the behavior changes from WLF to Arrhenius, and M …

Arrhenius equationMaterials scienceTheta solventThermodynamicsCondensed Matter PhysicsMethacrylatePoly n-butyl methacrylatePropanolShear (sheet metal)symbols.namesakechemistry.chemical_compoundchemistryPolymer chemistrysymbolsStationary flowGeneral Materials ScienceGlass transitionRheologica Acta
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Probing Poly(n-butyl-methacrylate) Latex Film via Diffusion of Hydrophilic and Hydrophobic Dye Molecules

2003

In the study of holographic grating relaxation (forced Rayleigh scattering, FRS) in nascent latex films we examined poly(n-butyl methacrylate) films using two complementary diffusing probes:  a hyd...

Polymers and PlasticsHolographic gratingChemistryDiffusionOrganic ChemistryRelaxation (NMR)MethacrylatePoly n-butyl methacrylateInorganic Chemistrysymbols.namesakePolymer chemistryMaterials ChemistrysymbolsMoleculeForced Rayleigh scatteringRayleigh scatteringMacromolecules
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